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CAS: 611-73-4
分子式: C8H6O3
分子量: 150.13
沸点: 84℃
熔点: 67-69℃
中文名称: 
苄基甲酸
苯甲酰甲酸
苯乙酮酸
英文名称: 
benzeneglyoxylic acid
alpha-ketophenylacetic acid
alpha-oxobenzeneacetic acid
alpha-oxo-benzeneacetic aci
benzoylformic acid
phenyl-glyoxylic aci
oxophenylacetic acid
phenylglyoxylic acid
phenyloxoacetic acid
Benzoyl formic acid
-Oxobenzeneacetic
展开更多英文名
性质描述: 无色晶体。熔点66℃,沸点147.5℃(1.6kPa),在常压下蒸馏分解。能溶于水、酸、醚和热的四氯化碳。
生产方法: 由苯甲酰氰用浓盐酸水解而得。
用途: 精细化学品的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P792743MACKLIN苯甲酰甲酸10mM in DMSO185元/1ml;   展开
储存:-20°C, 干燥, 避光
P815414MACKLIN苯甲酰甲酸>95.0%(GC)27元/1g;   38元/5g;   143元/25g;   558元/100g;   2390元/500g;   4288元/1kg;   展开
储存:室温
状态:无色到白色到黄色到绿色固体
B1129TCIBenzoylformic Acid>97.0%(GC)(T)410元/5G;   1400元/25G;   展开

基本信息

纯度/分析方法>97.0%(GC)(T)
分子式/分子量C8H6O3 = 150.13
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (吸湿)
Reaxys-RN606718
PubChem物质ID87564072
SDBS (AIST Spectral DB)12538
MDL编号MFCD00002575

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 97.0 %
Purity(Neutralization titration)min. 97.0 %
Melting point61.0 to 67.0 ℃

物性(参考值)

熔点66 ℃
沸点138 ℃/12 mmHg
水溶性可溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#DA1480000
L00648Alfa AesarPhenylglyoxylic Acid98%870元/5g;   2840元/25g;   展开

基本信息

MDL
MFCD00002575

EINECS
210-278-7

分子式
C8H6O3

分子量
150.13

熔点
62-67°

沸点
147-151°/12mm

密度
1.38

Beilstein
606718

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
DA1480000

TSCA

C10576Alfa AesarBenzoylformic Acid97%866元/5g;   2723元/25g;   7926元/100g;   展开

基本信息

Ref#
10576

MDL
2575

分子式
C8 H6 O3

分子量
150.13

78610Sigma-AldrichPhenylglyoxylic Acidpurum, ≥98.0% (T)811.28元/10 G;   展开

产品说明

其他说明

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 78610.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

基本信息

线性分子式C6H5COCOOH
分子量150.13
Beilstein606718
EC 号210-278-7
MDL编号MFCD00002575
PubChem化学物质编号329768165
NACRESNA.22

产品性质

质量水平200
等级purum
测定≥98.0% (T)
bp84 ℃/0.1 mmHg
mp62-65 ℃ (lit.)
63-67 ℃
溶解性methanol: 0.1 g/mL, clear
SMILES stringOC(=O)C(=O)c1ccccc1
InChI1S/C8H6O3/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5H,(H,10,11)
InChI keyFAQJJMHZNSSFSM-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
B13055Sigma-AldrichPhenylglyoxylic Acid97%436.9元/5 G;   1604.75元/25 G;   3575.64元/100 G;   展开

产品说明

应用

苯乙醛酸可作为前驱体用于合成:

  • 邻乙酰乙酰苯胺,使用 Pd 催化剂进行乙酰苯胺的脱羧邻酰化。
  • 通过高真空闪速热解合成苯羟基碳。
  • 使用草酸铌铵(ANO)作为催化剂与邻胺苯硫酚发生反应,合成 2-芳基苯并噻唑。
  • 在草酸铌铵催化剂存在时,通过邻氨基苯酚处理合成 3-芳基-2H-苯并[b][1,4]苯并恶嗪-2-酮。
  • 通过苯并噻唑的过硫酸钾(K2S2O8)-介导氧化缩合合成 2-芳基苯并噻唑。

包装

5 g in glass bottle
25, 100 g in poly bottle

基本信息

线性分子式C6H5COCOOH
分子量150.13
Beilstein606718
EC 号210-278-7
MDL编号MFCD00002575
PubChem化学物质编号24891579
NACRESNA.22

产品性质

质量水平200
测定97%
mp62-65 ℃ (lit.)
SMILES stringOC(=O)C(=O)c1ccccc1
InChI1S/C8H6O3/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5H,(H,10,11)
InChI keyFAQJJMHZNSSFSM-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
990638AmethystBenzoylformic Acid98%, 用于合成244元/5G;   603元/25G;   887元/100G;   展开

基本信息

分子式C8H6O3
分子量150.13
熔点62-65
沸点138
密度1.38
MDL编码MFCD00002575
Beilstein606718
EINECS 编号210-278-7

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSDA1480000
024966FluorochemPhenylglyoxylic Acid95+%220元/1g;   396元/5g;   1122元/25g;   2794元/100g;   展开

基本信息

CAS Number611-73-4
MDL NumberMFCD00002575
Boiling Point84 ℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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