| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| D807807 | MACKLIN | 2-双环己基膦-2 ',6'-二异丙氧基联苯 | 98% | 28元/250mg; 32元/1g; 68元/5g; 288元/25g; 1088元/100g; 4520元/500g; | 展开 |
储存：2~8℃,干燥,密封 状态：白色到灰白色结晶粉末 |
| D5037 | TCI | 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl | >98.0%(T)(HPLC) | 1590元/1G; 5380元/5G; | 展开 |
基本信息 | 纯度/分析方法 | >98.0%(T)(HPLC) | | 分子式/分子量 | C30H43O2P = 466.65 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 9880517 | | PubChem物质ID | 354334781 | | MDL编号 | MFCD06798294 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(HPLC) | min. 98.0 area% | | Purity(Nonaqueous Titration) | min. 98.0 % | | Melting point | 123.0 to 127.0 ℃ |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H413 : 可能对水生生物造成长期持续有害影响。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 15-1146 | Strem | 2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl | min. 98% | 825元/1g; 3555元/5g; 13005元/25g; 22680元/100g; | 展开 |
Technical Notes : 1. Versatile L igand for the Pd-catalyzed coupling of secondary arylamines and alkylamines. a.See also 46-0266, 46-0366 b.See reference 7, 8 2.Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero )arylchlorides. 3. Synthesis of ladder-type TT-conjugated heteroacenes via palladium- catalyzed double N-arylation and intramolecular o arylation. 4.A palladium-catalyzed regiospecific synthesis of N-aryI benzimidazoles, 5.Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst 6.Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes . 7.Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides. 8.Ligand used for the palladium- catalyzed coupling of alkyl boronates . |
| 663131 | Sigma-Aldrich | RuPhos | 98% | 657.6元/1 G; 2419.53元/5 G; 7959.12元/25 G; 10096.8元/100 G; | 展开 |
产品说明 包装 1, 5, 25, 100 g in glass bottle 应用 大位阻膦配体，可用于氨基乙基三氟硼酸酯与缺电子芳基溴的钯催化交叉偶联反应。 法律信息 专利使用：EP 1097158；JP 5758844；CA 2336691 基本信息 | 经验(实验)分子式 | C30H43O2P | | 分子量 | 466.64 | | MDL编号 | MFCD06798294 | | PubChem化学物质编号 | 24884189 | | NACRES | NA.22 |
产品性质 | 质量水平 | 300 | | 测定 | 98% | | reaction suitability | reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling | | 环保替代产品得分 | old score: 3
new score: 1
Find out more about DOZN™ Scoring | | 环保替代产品特性 | Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry. | | 杂质 | 1-5% Bis(2′,6′-Diisopropoxybiphenyl)cyclohexylphosphine | | mp | 123-126 ℃ | | 官能团 | phosphine | | 环保替代产品分类 | Re-engineered | | SMILES string | CC(C)Oc1cccc(OC(C)C)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4 | | InChI | 1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3 | | InChI key | MXFYYFVVIIWKFE-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable |
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| 901907 | Sigma-Aldrich | RuPhos | 95% | 687.62元/1 G; 2574.73元/5 G; 5881.22元/25 G; | 展开 |
产品说明 应用 用于氨基乙基三氟硼酸酯与贫电子芳基溴化物的钯催化交叉偶联的块状膦配体。 法律信息 专利使用：EP 1097158；JP 5758844；CA 2336691 基本信息 | 经验(实验)分子式 | C30H43O2P | | 分子量 | 466.64 | | MDL编号 | MFCD06798294 |
产品性质 | 测定 | 95% | | 形式 | powder or crystals | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | | mp | 123-126 ℃
125 ℃ | | 官能团 | phosphine | | SMILES string | CC(C)Oc1cccc(OC(C)C)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4 | | InChI | 1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3 | | InChI key | MXFYYFVVIIWKFE-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable |
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| 051167 | Fluorochem | 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl | 97% | 374元/1g; 990元/5g; | 展开 |
基本信息 | CAS Number | 787618-22-8 | | MDL Number | MFCD06798294 | | Boiling Point | 551.7℃ | | Melting Point | 123-127℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
H413: May cause long lasting harmful effects to aquatic life.
| | 防范说明 | P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to local regulations.
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